The enantioselective total synthesis of nemotin.
نویسندگان
چکیده
The allene-diyne natural product nemotin was synthesized for the first time through an enantioselective route with the stereogenic center at the lactone moiety derived from l-glutamic acid and the allene axis constructed from the corresponding propargylic tosylate, and the absolute configuration was thus established as (4S,5aS).
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عنوان ژورنال:
- Organic & biomolecular chemistry
دوره 8 4 شماره
صفحات -
تاریخ انتشار 2010